I believe I found a workaround based on the sources in the question link that was mentioned in my opening question.
Entering the following in terminalTerminal followed by enterEnter will make changes to ~/Library/Preferences/.GlobalPreferences.plist~/Library/Preferences/.GlobalPreferences.plist
(this is a hidden file revealed with command + shift + .Cmd+Shift+. if manually browsed to in a Finder window via GoGo > Go to FolderGo to Folder)
defaults write -g AppleICUTimeFormatStrings -dict-add 1 "hh':'mm':'ss' 'a"
defaults write -g AppleICUTimeFormatStrings -dict-add 1 "hh':'mm':'ss' 'a"
After force-quit restarting the Finder, the desired time format with seconds is now working perfectly.