As has been mentioned, you can'tcouldn't daisy-chain multiple Thunderbolt displays to an Airon pre-2012 Airs. Two possible add-ons that'll allow you to connect an additional external display:
- Matrox DualHead2Go (in action hooked up to an 11" Air)
- DisplayLink adapter
I've used the latter and they work pretty well for non-intensive applications.